Fibre-reactive dyes, their preparation and their use

ABSTRACT

Reactive dyes of formula (1) wherein Q 1 , Q 2 , Q 3  and Q 4  are each independently of the others hydrogen or unsubstituted or substituted C 1 –C 4 alkyl, A is the radical of a monoazo, polyazo, metal complex azo, anthraquinone, phthalocyanine, formazan or dioxazine chromophore, D is the radical of a diazo component, of the benzene or naphthalene series, X is halogen, 3-carboxpyridin-1-yl, 3-carbamoylpyridin-1-yl, hydroxy, C 1 –C 4 alkoxy unsubstituted or substituted in the alkyl moiety, phenoxy unsubstituted or substituted in the phenyl moiety, C 1 –C 4 alkylthio unsubstituted or substituted in the alkyl moiety, unsubstituted or substituted amino, or an N-heterocycle which may or may not contain further hetero atoms, and Y is vinyl or a radical —CH 2 —CH 2 —U and U is a group removable under alkaline conditions, are suitable for dyeing cellulosic or amide-group-containing fibre materials.

The present invention relates to fibre-reactive dyes, to processes for the preparation thereof and to the use thereof in dyeing or printing textile fibre materials.

The practice of dyeing using reactive dyes has recently led to higher demands being made of the quality of the dyeings and the profitability of the dyeing process. As a result, there is still a need for novel reactive dyes having improved properties, especially in respect of their application.

Dyeing nowadays requires reactive dyes that have sufficient substantivity and at the same time have good ease of washing off of unfixed dye. They should also have a good tinctorial yield and high reactivity, the objective being to provide especially dyeings having high degrees of fixing. The known dyes do not satisfy these requirements in all properties.

The problem underlying the present invention is accordingly to find, for the dyeing and printing of fibre materials, novel improved reactive dyes having the qualities characterised above to a high degree. The novel dyes should especially be distinguished by high fixing yields and high fibre-dye binding stability; it should also be possible for dye that is not fixed to the fibre to be washed off easily. The dyes should also yield dyeings having good all-round fastness properties, for example light-fastness and wet-fastness properties.

It has been shown that the problem posed is largely solved by the novel dyes defined below.

The present invention accordingly relates to reactive dyes of formula (1)

wherein

-   Q₁, Q₂, Q₃ and Q₄ are each independently of the others hydrogen or     unsubstituted or substituted C₁–C₄alkyl, -   A is the radical of a monoazo, polyazo, metal complex azo,     anthraquinone, phthalocyanine, formazan or dioxazine chromophore, -   D is the radical of a diazo component, of the benzene or naphthalene     series, -   X is halogen, 3carboxypyridin-1-yl, 3-Carbamoylpyridin-1-yl,     hydroxy, C₁–C₄alkoxy unsubstituted or substituted in the alkyl     moiety, phenoxy unsubstituted or substituted in the phenyl moiety,     C₁–C₄alkylthio unsubstituted or substituted in the alkyl moiety,     unsubstituted or substituted amino, or an N-heterocycle which may or     may not contain further hetero atoms, and -   Y is vinyl or a radical —CH₂—CH₂-U and U is a group removable under     alkaline conditions.

The radicals Q, Q₂, Q₃ and Q₄ as alkyl radicals are straight-chained or branched. The alkyl radicals may be further substituted, for example by hydroxy, sulfo, sulfato, cyano or by carboxy. The following radicals may be mentioned as examples: methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, sec-butyl and tert-butyl, and also the corresponding radicals substituted by hydroxy, sulfo, sulfato, cyano or by carboxy. Preference is given to hydroxy, sulfo, sulfato or carboxy as substituents. In the case of the alkyl radicals Q₁ and Q₂, special preference is given to hydroxy or sulfato as substituent. In the case of the alkyl radicals Q₃ and Q₄, special preference is given to carboxy as substituent.

Q₁, Q₂, Q₃ and Q₄ preferably are each independently of the others hydrogen or C₁–C₄alkyl, especially hydrogen, methyl or ethyl, the alkyl radicals being unsubstituted or substituted by hydroxy, sulfo, sulfato or by carboxy; more especially, Qis hydrogen, methyl or ethyl, Q₂ is hydrogen, and Q₃ and Q₄ are hydrogen or unsubstituted or carboxy-substituted methyl or ethyl.

Very especially, Q₁, Q₂, Q₃ and Q₄ are hydrogen.

X as halogen is, for example, fluorine, chlorine or bromine, and especially chlorine or fluorine.

X as C₁–C₄alkoxy is, for example, methoxy, ethoxy, n- or iso-propoxy, n-, sec-, iso- or tert-butoxy, preferably methoxy, ethoxy or isopropoxy, and especially methoxy. The mentioned radicals are unsubstituted or substituted in the alkyl moiety, for example by C₁–C₄alkoxy, hydroxy, sulfo or by carboxy. Preference is given to the unsubstituted radicals.

X as phenoxy is unsubstituted or substituted in the phenyl moiety, for example by C₁–C₄alkyl, C₁–C₄alkoxy, C₂–C₄alkanoylamino, hydroxy, sulfo or by carboxy. Preference is given to the unsubstituted or sulfo-substituted radicals.

X as C₁–C₄alkylthio is, for example, methylthio, ethylthio, n-propylthio, isopropylthio or n-butylthio, especially methylthio or ethylthio. The mentioned radicals are unsubstituted or substituted in the alkyl moiety, for example by hydroxy, carboxy or by sulfo. Preference is given to the unsubstituted radicals.

X as unsubstituted or substituted amino is amino unsubstituted or substituted at the N atom, for example one of the following radicals:

-   N-mono- or N,N-di-C₁–C₄alkylamino, which includes radicals that are     unsubstituted, and uninterrupted or interrupted in the alkyl moiety     by oxygen, and also radicals substituted in the alkyl moiety, for     example by C₂–C₄alkanoylamino, C₁–C₄alkoxy, hydroxy, sulfo, sulfato,     carboxy, cyano, carbamoyl or by sulfamoyl, preferably by     C₁–C₄alkoxy, hydroxy, sulfo or by sulfato; preference is given to     the radicals substituted in the alkyl moiety; as examples there may     be mentioned N-methylamino, N-ethylamino, N-propylamino,     N,N-di-methylamino or N,N-di-ethylamino, Nβ-hydroxyethylamino,     N,N-di-β-hydroxyethylamino, N-2-(β-hydroxy-ethoxy)ethylamino,     N-2-[2-(β-hydroxyethoxy)ethoxy]ethylamino, N-β-sulfatoethylamino,     N-β-sulfoethylamino, N-carboxymethylamino, N-β-carboxyethylamino,     N-α,β-dicarboxy-ethylamino, N-α,γ-dicarboxypropylamino,     N-ethyl-N-β-hydroxyethylamino or N-methyl-N-β-hydroxyethylamino; -   C₅–C₇cycloalkylamino, which includes both the unsubstituted radicals     and the radicals substituted in the cycloalkyl ring, for example by     C₁–C₄alkyl, especially methyl, or by carboxy; the corresponding     cyclohexyl radicals are preferred as such radicals; -   phenylamino or N—C₁–C₄alkyl-N-phenylamino, which include both the     unsubstituted radicals and the radicals substituted in the phenyl     ring, for example by C₁–C₄alkyl, C₁–C₄alkoxy, C₂–C₄alkanoylamino,     carboxy, carbamoyl, sulfo or by halogen, or In the alkyl, for     example by hydroxy, sulfo or by sulfato, such as, for example, 2-,     3- or 4-chlorophenylamino, 2-, 3- or 4-methylphenylamino, 2-, 3- or     4-methoxyphenylamino, 2-, 3- or 4-sulfophenylamino,     disulfo-phenylamino, or 2-, 3- or 4-carboxyphenyl-amino; preferably,     those radicals are, in the phenyl ring, unsubstituted or substituted     by sulfo; naphthylamino unsubstituted or substituted in the naphthyl     ring, for example by sulfo, preferably the radicals substituted by     from 1 to 3 sulfo groups, such as, for example, 1- or     2-naphthylamino, 1-sulfo-2-naphthylamino,     1,5-disulfo-2-naphthylamino or 4,8-disulfo-2-naphthylamino; or -   benzylamino unsubstituted or substituted in the phenyl moiety, for     example by C₁–C₄alkyl, C₁–C₄alkoxy, carboxy, sulfo or by halogen.

N-heterocycles which may or may not contain further hetero atoms and which are suitable as X are, for example, morpholino or piperidin-1-yl, preferably morpholino.

X is preferably fluorine, chlorine, C₁–C₄alkoxy, C₁–C₄alkylthio, hydroxy, amino; N-mono- or N,N-di-C₁–C₄alkylamino unsubstituted or substituted in the alkyl moiety by hydroxy, sulfato or by sulfo; morpholino; phenylamino or N—C₁–C₄alkyl-N-phenylamino (wherein the alkyl is unsubstituted or substituted by hydroxy, sulfo or by sulfato) unsubstituted or substituted in the phenyl ring by sulfo, carboxy, acetylamino, chlorine, methyl, ethyl, methoxy or by ethoxy; or unsubstituted or mono- to tri-sulfo-substituted naphthylamino.

X is especially fluorine, chlorine, amino, N-methylamino, N-ethylamino, N-β-hydroxyethyl-amino, N-methyl-N-β-hydroxyethylamino, N-ethyl-N-β-hydroxyethylamino, N,N-di-β-hydroxy-ethylamino, morpholino, 2-, 3- or 4-sulfophenylamino or N—C₁–C₄alkyl-N-phenylamino.

X is very especially fluorine, chlorine, amino, N-β-hydroxyethylamino, N,N-di-β-hydroxyethyl-amino, morpholino or 2-, 3- or 4-sulfophenylamino.

X in the meaning of fluorine or chlorine, especially chlorine, is very especially important.

As a group removable under alkaline conditions, U may be, for example, —Cl, —Br, —F, —OSO₃H, —SSO₃H, —OCO—CH₃, —OPO₃H₂, —OCO—C₆H₅, —OSO₂—C₁–C₄alkyl or —OSO₂—N(C₁–C₄alkyl)₂. U is preferably a group of formula —Cl, —OSO₃H, —SSO₃H, —OCO—CH₃, —OCO—C₆H₅ or —OPO₃H₂, especially —Cl or —OSO₃H, and more especially —OSO₃H.

Examples of suitable radicals Y are accordingly vinyl, β-bromo- or β-chloro-ethyl, β-acetoxy-ethyl, β-benzoyloxyethyl, β-phosphatoethyl, β-sulfatoethyl and β-thiosulfatoethyl. Y is preferably vinyl, β-chloroethyl or β-sulfatoethyl, and especially vinyl or β-sulfatoethyl.

Suitable substituents of the radical D include the substituents customary for azo dyes. The following may be mentioned by way of example: C₁–C₄alkyl, which is to be understood as being methyl, ethyl, n- or iso-propyl, and n-, iso-, sec- or tert-butyl; C₁–C₄alkoxy, which is to be understood as being methoxy, ethoxy, n- or iso-propoxy, and n-, iso-, sec- or tert-butoxy; hydroxy-C₁–C₄alkoxy; phenoxy; C₂–C₆alkanoylamino unsubstituted or substituted in the alkyl moiety by hydroxy or by C₁–C₄alkoxy, e.g. acetylamino, hydroxyacetylamino, methoxyacetyl-amino or propionylamino; benzoylamino unsubstituted or substituted in the phenyl moiety by hydroxy, sulfo, halogen, C₁–C₄alkyl or by C₁–C₄alkoxy; C₁–C₆alkoxycarbonylamino unsubstituted or substituted in the alkyl moiety by hydroxy, C₁–C₄alkyl or by C₁–C₄alkoxy; phenoxycarbonylamino unsubstituted or substituted in the phenyl moiety by hydroxy, C₁–C₄alkyl or by C₁–C₄alkoxy; amino; N—C₁–C₄alkyl- or N,N-di-C₁–C₄alkyl-amino unsubstituted or substituted in the alkyl moiety by hydroxy, C₁–C₄alkoxy, carboxy, cyano, halogen, sulfo, sulfato, phenyl or by sulfophenyl, e.g. methylamino, ethylamino, N,N-dimethylamino, N,N-diethylamino, β-cyanoethylamino, β-hydroxyethylamino, N,N-di-β-hydroxyethylamino, βsulfoethylamino, γ-sulfo-n-propylamino, β-sulfatoethylamino, N-ethyl-N-(3-sulfobenzyl)-amino, N-(β-sulfoethyl)-N-benzylamino; cyclohexylamino; N-phenylamino or N—C₁–C₄alkyl-N-phenylamino unsubstituted or substituted in the phenyl moiety by nitro, C₁–C₄alkyl, C₁–C₄alkoxy, carboxy, halogen or by sulfo; C₁–C₄alkoxycarbonyl, e.g. methoxy- or ethoxy-carbonyl; trifluoromethyl; nitro; cyano; halogen, which is to be understood generally as being, for example, fluorine, bromine or, especially, chlorine; ureido; hydroxy; carboxy; sulfo; sulfomethyl; carbamoyl; carbamido; sulfamoyl; N-phenylsulfamoyl or N—C₁–C₄alkyl-N-phenylsulfamoyl unsubstituted or substituted in the phenyl moiety by sulfo or by carboxy; methyl- or ethyl-sulfonyl.

Suitable substituents of the radical D also include fibre-reactive radicals.

Fibre-reactive radicals are to be understood as being those which are capable of reacting with the hydroxy groups of cellulose, with the amino, carboxy, hydroxy and thiol groups in wool and silk or with the amino and possibly carboxy groups of synthetic polyamides to form covalent chemical bonds. The fibre-reactive radicals are generally bonded to the dye radical directly or via a bridging member. Suitable fibre-reactive radicals are, for example, those having at least one removable substituent at an aliphatic, aromatic or heterocyclic radical or those wherein the mentioned radicals contain a radical suitable for reaction with the fibre material, for example a vinyl radical.

A fibre-reactive radical present in D corresponds, for example, to formula (2a), (2b), (2c), (2d), (2e), (2f) or (2g) —SO₂-Y  (2a), —NH—CO—(CH₂)₁SO₂-Y  (2b), —CONR₂—(CH₂)_(m)—SO₂Y  (2c), —NH—CO—CH(Hal)-CH₂-Hal  (2d), —NH—CO—C(Hal)=CH₂  (2e),

wherein

-   Hal is chlorine or bromine, -   X₁ is halogen, 3-carboxypyridin-1-yl or 3-carbamoylpyridin-1-yl, -   T₁ has independently the same definitions as X₁, or is a     non-fibre-reactive substituent or a fibre-reactive radical of     formula (3a), (3b), (3c), (3d), (3e) or (3f)

wherein

-   R₁, R_(1a) and R_(1b) are each independently of the others hydrogen     or C₁–C₄alkyl, -   R₂ is hydrogen; C₁–C₄alkyl unsubstituted or substituted by hydroxy,     sulfo, sulfato, carboxy or by cyano; or a radical

-   R₃ is hydrogen, hydroxy, sulfo, sulfato, carboxy, cyano, halogen,     C₁–C₄alkoxycarbonyl, -   C₁–C₄alkanoyloxy, carbamoyl or a group —SO₂-Y, -   alk and alk₁ are each independently of the other linear or branched     C₁–C₆alkylene, arylene is a phenylene or naphthylene radical     unsubstituted or substituted by sulfo, carboxy, C₁–C₄alkyl,     C₁–C₄alkoxy or by halogen, -   Q is a radical —O— or —NR₁— wherein R₁ is as defined above, -   W is a group —SO₂—NR₂—, CONR₂— or —NR₂CO— wherein R₂ is as defined     above, -   Y is vinyl or a radical —CH₂CH₂-U and U is a group removable under     alkaline conditions, -   Y₁ is a group —CH(Hal)-CH₂-Hal or —C(Hal)=CH₂ and Hal is chlorine or     bromine, and -   1 and m are each independently of the other an integer from 1 to 6     and n is a number 0 or 1, and -   X₂ is halogen or C₁–C₄alkylsulfonyl, -   X₃ is halogen or C₁–C₄alkyl, and -   T₂ is hydrogen, cyano or halogen.

Y is as defined above and has the preferred meanings given above.

R₁, R_(1a) and R_(1b) preferably are each independently of the others hydrogen, methyl or ethyl, and especially hydrogen.

R₂ is preferably hydrogen or C₁–C₄alkyl, for example methyl, ethyl, propyl, isopropyl, butyl, isobutyl, sec-butyl or tert-butyl, and especially hydrogen, methyl or ethyl. R₂ is more especially hydrogen.

R₃ is preferably hydrogen.

1 and m preferably are each independently of the other a number 2, 3 or 4, and especially a number 2 or 3.

More especially, I is the number 3 and m is the number 2.

For a non-fibre-reactive substituent T₁ there come into consideration, for example, hydroxy or one of the radicals indicated above for X in the meaning of C₁–C₄-alkoxy unsubstituted or substituted in the alkyl moiety, phenoxy unsubstituted or substituted in the phenyl moiety, C₁–C₄alkylthio unsubstituted or substituted in the alkyl moiety, unsubstituted or substituted amino, or an N-heterocycle which may or may not contain further hetero atoms.

T₁ as a non-fibre-reactive radical is preferably C₁–C₄alkoxy, C₁–C₄alkylthio, hydroxy, amino; N-mono- or N,N-di-C₁–C₄alkylamino unsubstituted or substituted in the alkyl moiety by hydroxy, sulfato or by sulfo; morpholino; or phenylamino or N—C₁–C₄alkyl-N-phenylamino (wherein the alkyl is unsubstituted or substituted by hydroxy, sulfo or by sulfato) each unsubstituted or substituted in the phenyl ring by sulfo, carboxy, acetylamino, chlorine, methyl or by methoxy; or naphthylamino unsubstituted or substituted by from 1 to 3 sulfo groups.

Especially preferred non-fibre-reactive radicals T₁ are amino, N-methylamino, N-ethylamino, N-β-hydroxyethylamino, N-methyl-Nβ-hydroxyethylamino, N-ethyl-N-β-hydroxyethylamino, N,N-di-β-hydroxyethylamino, morpholino, 2-, 3- or 4-carboxyphenylamino, 2-, 3- or 4-sulfo-phenylamino or N—C₁–C₄alkyl-N-phenylamino.

X₁ is preferably halogen, for example fluorine, chlorine or bromine and especially chlorine or fluorine.

T₂, X₂ and X₃ as halogen are, for example, fluorine, chlorine or bromine, especially chlorine or fluorine.

X₂ as C₁–C₄alkylsulfonyl is, for example, ethylsulfonyl or methylsulfonyl and especially methylsulfonyl.

X₃ as C₁–C₄alkyl is, for example, methyl, ethyl, n- or iso-propyl, n-, iso- or tert-butyl and especially methyl.

-   X₂ and X₃ are preferably each independently of the other chlorine or     fluorine. -   T₂ is preferably cyano or chlorine. -   Hal is preferably bromine. -   alk and alk₁ are each independently of the other, for example, a     methylene, ethylene, 1,3-propylene, 1,4-butylene, 1,5-pentylene or     1,6hexylene radical or a branched isomer thereof. -   alk and alk₁ are preferably each independently of the other a     C₁–C₄alkylene radical and especially an ethylene radical or     propylene radical. -   arylene is preferably a 1,3- or 1,4-phenylene radical unsubstituted     or substituted, for example, by sulfo, methyl, methoxy or by     carboxy, and especially an unsubstituted 1,3- or 1,4-phenylene     radical. -   Q is preferably —NH— or —O— and especially —O—. -   W is preferably a group of formula —CONH— or —NHCO—, especially a     group of formula —CONH—. -   n is preferably the number 0.

The reactive radicals of formulae (3a) to (3f) are preferably those wherein W is a group of formula —CONH—, R₁, R₂ and R₃ are each hydrogen, Q is a radical —O— or NH—, alk and alk₁ are each independently of the other ethylene or propylene, arylene is phenylene unsubstituted or substituted by methyl, methoxy, carboxy or by sulfo, Y is vinyl or β-sulfatoethyl, Y₁ is —CHBr—CH₂Br or —CBr═CH₂ and n is the number 0.

A fibre-reactive radical present in D corresponds preferably to a radical of formula (2a), (2b), (2c), (2d), (2e) or (2f) wherein Y is vinyl, β-chloroethyl or β-sulfatoethyl, Hal is bromine, R₂ and R_(1a) are hydrogen, m and 1 are a number 2 or 3, X₁ is halogen, T₁ is C₁–C₄alkoxy, C₁–C₄alkylthio, hydroxy, amino; N-mono- or N,N-di-C₁–C₄alkylamino unsubstituted or substituted in the alkyl moiety by hydroxy, sulfato or by sulfo; morpholino; or phenylamino or N—C₁–C₄alkyl-N-phenylamino (wherein the alkyl is unsubstituted or substituted by hydroxy, sulfo or by sulfato) each unsubstituted or substituted in the phenyl ring by sulfo, carboxy, acetylamino, chlorine, methyl or by methoxy; or naphthylamino unsubstituted or substituted by from 1 to 3 sulfo groups, or is a fibre-reactive radical of formula (3a′), (3b′), (3c′), (3d′) or (3f′) —NH—(CH₂)₂₋₃—SO₂Y  (3a′), —NH—(CH₂)₂₋₃—O—(CH₂)₂₋₃—SO₂Y  (3b′),

especially (3c′) or (3d′), wherein

-   Y is as defined above, and -   Y₁ is a group —CH(Br)—CH₂—Br or —C(Br)═CH₂.

In the case of the radicals of formulae (3a′) and (3b′), Y is preferablyβ-chloroethyl. In the case of the radicals of formulae (3c′) and (3d′), Y is preferably vinyl or β-sulfatoethyl.

A particular embodiment of the present invention relates to dyes wherein a radical present in D corresponds to formula (2h)

wherein

-   R_(1a) and X₁ are as defined above and have the preferred meanings     given above, and -   T₃ is a monoazoamino or disazoamino radical of formula (4) or (5)     D₁-N═N-(M-N═N)_(u)—K₁—NR₁—  (4) or     —NR₁-D₁-N═N-(M-N═N)_(u)—K₁  (5)     wherein -   D₁ is the radical of a diazo component, of the benzene or     naphthalene series, M is the radical of a central component, of the     benzene or naphthalene series, K₁ is the radical of a coupling     component, of the benzene, naphthalene, pyrazolone,     6-hydroxypyrid-2-one or acetoacetic acid arylamide series, R₁ is as     defined above and has the preferred meanings given above and u is a     number 0 or 1, wherein D₁, M and K₁ may carry substituents customary     for azo dyes.

The expression “substituents customary for azo dyes” is intended to include both fibre-reactive and non-fibre-reactive substituents, for example the substituents mentioned above for D.

As non-fibre-reactive substituents for D₁, M and K₁ in T₃ there come into consideration preferably C₁–C₄alkyl or C₁–C₄alkoxy unsubstituted or further substituted by hydroxy, sulfo or by sulfato; halogen, carboxy, sulfo, nitro, cyano, trifluoromethyl, sulfamoyl, carbamoyl, amino, ureido, hydroxy, sulfomethyl, C₂–C₄alkanoylamino; benzoylamino unsubstituted or substituted in the phenyl ring by C₁–C₄alkyl, C₁–C₄alkoxy, halogen or by sulfo; or phenyl unsubstituted or substituted by C₁–C₄alkyl, C₁–C₄alkoxy, halogen, carboxy or by sulfo.

The monoazoamino or disazoamino radicals of formula (4) or (5) preferably contain at least one sulfo group.

Preferred monoazoamino or disazoamino radicals T₃ are the radicals of formulae (6a), (6b), (6c), (6d), (6e), (6f), (6g), (6h), (6i), (6j), (6k), (6l), (6m), (6n), (6o) and (6p)

wherein (R₄)₀₋₃ denotes from 0 to 3 identical or different substituents from the group C₁–C₄alkyl, C₁–C₄alkoxy, halogen, carboxy and sulfo,

-   (R₅)₀₋₃ denotes from 0 to 3 identical or different substituents from     the group halogen, nitro, cyano, trifluoromethyl, sulfamoyl,     carbamoyl, C₁–C₄alkyl; C₁–C₄alkoxy unsubstituted or substituted by     hydroxy, sulfato or by C₁–C₄alkoxy; amino, C₂–C₄alkanoylamino,     ureido, hydroxy, carboxy, sulfomethyl, C₁–C₄alkylsulfonylamino and     sulfo, and -   Z₁ is a radical of formula (2a), (2c), (2d), (2e), (2f) or (2g),     preferably (2a), (2c), (2d) or (2e) and especially (2a), the     mentioned radicals having the definitions and preferred meanings     given above,

wherein R₆ is C₂–C₄alkanoyl, benzoyl or a radical of formula (2b) or (2f) indicated above wherein the radicals are as defined above and have the preferred meanings given above, preferably C₂–C₄alkanoyl or benzoyl,

wherein (R₇)₀₋₃ denotes from 0 to 3 identical or different substituents from the group C₁–C₄alkyl, C₁–C₄alkoxy, halogen, carboxy and sulfo,

wherein R₈ and R₁₀ are each independently of the other hydrogen, C₁–C₄alkyl or phenyl, and R₉ is hydrogen, cyano, carbamoyl or sulfomethyl,

wherein

-   (R₄)₀₋₃, (R₅)₀₋₃and (R₇)₀₋₃ are each as defined above, -   (R₁₁)₀₋₃ and (R₁₂)₀₋₃ each independently of the other denote from 0     to 3 identical or different substituents from the group C₁–C₄alkyl,     C₁–C₄alkoxy, halogen, carboxy and sulfo, and Z₁ is as defined above     and has the preferred meanings given above.

The numbers on the naphthyl rings of the radicals of formulae (6a), (6b), (6c), (6d), (6e), (6g) and (6h) indicate the possible bonding positions.

-   (R₄))₀₋₃ in the disazoamino radicals of formulae (6n) and (6p)     preferably denotes from 0 to 3 sulfo groups.

Especially preferred monoazoamino or disazoamino radicals T₃ are the radicals of formulae (6a), (6b), (6d), (6e), (6f), (6k) and (6m), especially (6b), (6k) and (6m).

D is, for example, phenyl or naphthyl, each of which is unsubstituted or is substituted, for example by C₁–C₄alkyl, C₁–C₄alkoxy, halogen, sulfo, nitro, carboxy or by a fibre-reactive radical of formula (2a), (2b), (2c), (2d), (2e), (2f) or (2g), especially (2a), (2c), (2d), (2e) or (2f), the mentioned fibre-reactive radicals having the definitions and preferred meanings given above.

D also includes monoazo radicals, for example those of formula (7) or (8) -D₂-N═N—K₂  (7) or D₂-N═N—K₃—  (8), preferably of formula (8), wherein D₂ is the radical of a diazo component, of the benzene or naphthalene series, K₂ is the radical of a coupling component, of the benzene, naphthalene, pyrazolone, 6-hydroxypyrid-2-one or acetoacetic acid arylamide series, and K₃ is the radical of a coupling component, of the benzene or naphthalene series, wherein D₂, K₂ and K₃ may carry substituents customary for azo dyes.

The expression “substituents customary for azo dyes” is intended to include both fibre-reactive and non-fibre-reactive substituents, for example the substituents mentioned above for D.

As non-fibre-reactive substituents for D₂, K₂ and K₃ there come into consideration preferably C₁–C₄alkyl or C₁–C₄alkoxy each unsubstituted or further substituted by hydroxy, C₁–C₄alkoxy, sulfo or by sulfato; halogen, carboxy, sulfo, nitro, cyano, trifluoromethyl, sulfamoyl, carbamoyl, amino, ureido, hydroxy, sulfomethyl, C₂–C₄alkanoylamino, C₁–C₄alkylsulfonyl-amino; benzoylamino unsubstituted or substituted in the phenyl ring by C₁–C₄alkyl, C₁–C₄alkoxy, halogen or by sulfo; or phenyl unsubstituted or substituted by C₁–C₄alkyl, C₁–C₄alkoxy, halogen, carboxy or by sulfo.

As fibre-reactive substituents for D₂, K₂ and K₃ there come into consideration preferably the radicals of formulae (2a), (2b), (2c), (2d), (2e) and (2f), especially (2a) and (2f) and more especially (2a), the mentioned radicals having the definitions and preferred meanings given above. In an interesting embodiment, preference is given to a radical of formula (2a) as fibre-reactive substituent for D₂ and to a radical of formula (2f) as fibre-reactive substituent for K₈.

The monoazo radicals of formulae (7) and (8) preferably contain at least one sulfo group.

Preferred monoazo radicals D of formula (8) correspond to the radicals of formulae (8a), (8b), (8c), (8d), (8e), (8f), (8g), (8h), (8i) and (8j)

wherein (R₄)₀₋₃ denotes from 0 to 3 identical or different substituents from the group C₁–C₄alkyl, C₁–C₄alkoxy, halogen, carboxy and sulfo, and Z₁ is a fibre-reactive radical of formula (2a), (2c), (2d), (2e), (2f) or (2g), preferably (2a), (2c), (2d) or (2e) and especially (2a), the mentioned fibre-reactive radicals having the definitions and preferred meanings given above,

wherein (R₄)₀₋₃ is as defined above, (R′₅)₀₋₃ denotes from 0 to 3 identical or different substituents from the group halogen, nitro, cyano, trifluoromethyl, sulfamoyl, carbamoyl, C₁–C₄alkyl; C₁–C₄alkoxy unsubstituted or substituted by hydroxy, sulfato or by C₁–C₄alkoxy; amino, C₂–C₄alkanoylamino, ureido, hydroxy, carboxy, sulfomethyl, C₁–C₄alkylsulfonylamino, sulfo and a fibre-reactive radical of formula (2f) wherein the radicals R_(1a), T₁ and X₁ are as defined above and have the preferred meanings given above and Z₁ is as defined above and has the preferred meanings given above.

The numbers on the naphthyl rings of the radicals of formulae (8a), (8b), (8e) and (8f) indicate the possible bonding positions.

The radical D preferably corresponds to a radical of formula (9) or (10)

wherein

-   (R₄)₀₋₃ and (R₁₃)₀₋₃ each independently of the other denote from 0     to 3 identical or different substituents selected from the group     halogen, C₁–C₄alkyl, C₁–C₄alkoxy, carboxy and sulfo, K₃ is the     radical of a coupling component of formula (11a) or (11b)

and

-   Z and Z₁ are each independently of the other a radical of formula     (2a), (2c), (2d), (2e) or (2f) indicated above, wherein -   R_(1a) and R₂ are hydrogen, -   Hal is bromine, -   Y is vinyl, β-chloroethyl or β-sulfatoethyl, -   T₁ is C₁–C₄alkoxy, C₁–C₄alkylthio, hydroxy, amino; N-mono- or     N,N-di-C₁–C₄alkylamino unsubstituted or substituted in the alkyl     moiety by hydroxy, sulfato or by sulfo; morpholino; or phenylamino     or N—C₁–C₄alkyl-N-phenylamino (wherein the alkyl is unsubstituted or     substituted by hydroxy, sulfo or by sulfato) each unsubstituted or     substituted in the phenyl ring by sulfo, carboxy, acetylamino,     chlorine, methyl or by methoxy; or naphthylamino unsubstituted or     substituted by from 1 to 3 sulfo groups, or is a fibre-reactive     radical of formula (3c′) or (3d′) indicated above, and Y is as     defined above, -   X₁ is chlorine or fluorine, -   m is a number 2 or 3, -   R′₅ is hydrogen, sulfo, or C₁–C₄alkoxy unsubstituted or substituted     in the alkyl moiety by hydroxy or by sulfato, -   R′_(5a) is hydrogen, C₁–C₄alkyl, C₁–C₄alkoxy, C₂–C₄alkanoylamino,     ureido or a radical of formula (2f) wherein the radicals R_(1a), T₁     and X₁ are as defined above and have the preferred meanings given     above. -   R₄, R′_(5a) and R₁₃ as C₁–C₄alkyl may be, each independently of the     others, for example, methyl, ethyl, n-propyl, isopropyl, n-butyl,     sec-butyl, tert-butyl or isobutyl, preferably methyl or ethyl and     especially methyl. -   R₄, R′₅, R′_(5a) and R₁₃ as C₁–C₄alkoxy may be, each independently     of the others, for example, methoxy, ethoxy, n-propoxy, isopropoxy,     n-butoxy or isobutoxy, preferably methoxy or ethoxy and especially     methoxy. R′₅ is unsubstituted or may be substituted in the alkyl     moiety by hydroxy or by sulfato. -   R₄ and R₁₃ as halogen may be, each independently of the other, for     example, fluorine, chlorine or bromine, preferably chlorine or     bromine and especially chlorine. -   R′_(5a) as C₂–C₄alkanoylamino may be, for example, acetylamino or     propionylamino, especially acetylamino. -   R′_(5a) as a radical of formula (2f) is preferably a radical wherein -   R_(1a) is hydrogen, -   T₁ is amino; N-mono- or N,N-di-C₁–C₄alkylamino unsubstituted or     substituted in the alkyl moiety by hydroxy, sulfato or by sulfo;     morpholino; or phenylamino or N—C₁–C₄alkyl-N-phenyl-amino (wherein     the alkyl is unsubstituted or substituted by hydroxy, sulfo or by     sulfato) each unsubstituted or substituted in the phenyl ring by     sulfo, carboxy, acetylamino, chlorine, methyl or by methoxy; or     naphthylamino unsubstituted or substituted by from 1 to 3 sulfo     groups, and -   X₁ is fluorine or chlorine.

In the radical of the coupling component of formula (11b), the sulfo group in ring ii is preferably bonded in the 3- or 4-position. When ring ii contains a sulfo group, the radical of formula (11b) is preferably bonded in the 1-, 2- or 3-position of ring ii. When ring ii does not contain a sulfo group, the radical of formula (11b) is preferably bonded in the 2- or 3-position of ring ii.

The radical D especially corresponds to a radical of formula (9a), (9b), (9c), (9d) or (10a)

wherein

-   R′₅ is hydrogen, sulfo, or ethoxy unsubstituted or substituted in     the alkyl moiety by hydroxy or by sulfato, -   R′_(5a) is hydrogen, methyl, ethyl, methoxy, ethoxy, acetylamino,     propionylamino or ureido, -   (R₁₃)₀₋₂ denotes from 0 to 2 identical or different substituents     selected from the group halogen, C₁–C₄alkyl, C₁–C₄alkoxy and sulfo,     especially methyl, methoxy and sulfo, -   Y₁ is a group —CH(Br)—CH₂—Br or —C(Br)═CH₂, -   Y is vinyl, β-chloroethyl or β-sulfatoethyl, especially vinyl or     β-sulfatoethyl, and -   m is a number 2 or 3, especially 2.

The numbers in the radicals of formulae (9a), (9c) and (9d) indicate the possible bonding positions of the fibre-reactive radical.

D is preferably a radical of formula (9a), (9b), (9c) or (10a), especially (9a) or (9c).

A is, for example, one of the following dye radicals:

-   a) dye radicals of a 1:1 copper complex azo dye, of the benzene or     naphthalene series, wherein the copper atom is bonded to a group     capable of being metallated on either side in the ortho-position to     the azo bridge -   b) dye radicals of a mono- or dis-azo dye of formula (12) or (13)     D₁-N═N-(M-N═N)_(u)—K₁-  (12) or     -D₁-N═N-(M-N═N)_(u)—K₁  (13),     or of a metal complex derived therefrom, wherein -   D₁ is the radical of a diazo component, of the benzene or     naphthalene series, M is the radical of a central component, of the     benzene or naphthalene series, K₁ is the radical of a coupling     component, of the benzene, naphthalene, pyrazolone,     6-hydroxypyrid-2-one or acetoacetic acid arylamide series, and u is     a number 0 or 1, wherein D₁, M and K₁ may carry substituents     customary for azo dyes -   c) dye radicals of a disazo dye of formula (14)     -D₃N═N—K₄—N═N-D₄  (14)     wherein D₃ and D₄ are each independently of the other the radical of     a diazo component, of the benzene or naphthalene series, and K₄ is     the radical of a coupling component, of the naphthalene series,     wherein D₃, D₄ and K₄ may carry substituents customary for azo dyes;     the expression “substituents customary for azo dyes” is intended to     include both fibre-reactive and non-fibre-reactive substituents, for     example the substituents mentioned above for D; -   d) dye radicals of a formazan dye of formula (15)

wherein the benzene rings contain no further substituents or are further substituted by C₁–C₄alkyl, C₁–C₄alkoxy, C₁–C₄alkylsulfonyl, halogen or by carboxy

-   e) dye radicals of an anthraquinone dye of formula (16)

wherein G is a phenylene radical unsubstituted or substituted by C₁–C₄alkyl, C₁–C₄alkoxy, halogen, carboxy or by sulfo or is a cyclohexylene, phenylenemethylene or C₂–C₈alkylene radical

-   f) dye radicals of a phthalocyanine dye of formula (17)

wherein Pc is the radical of a metal phthalocyanine, especially the radical of a copper or nickel phthalocyanine, W′ is —OH and/or —NR₁₅R₁₅′, R₁₅ and R₁₅′ are each independently of the other hydrogen or C₁–C₄alkyl unsubstituted or substituted by hydroxy or by sulfo, R₁₄ is hydrogen or C₁–C₄alkyl, E is a phenylene radical unsubstituted or substituted by C₁–C₄alkyl, halogen, carboxy or by sulfo or is a C₂–C₆alkylene radical, and k is from 1 to 3

-   g) dye radicals of a dioxazine dye of formula (18)

wherein E′ is a phenylene radical unsubstituted or substituted by C₁–C₄alkyl, halogen, carboxy or by sulfo or is a C₂–C₆alkylene radical, v and v′ are each independently of the other a number 0 or 1, and the outer benzene rings in formula (18) may be further substituted by C₁–C₄alkyl, C₁–C₄alkoxy, acetylamino, nitro, halogen, carboxy, sulfo or by a fibre-reactive radical of formula (2a), Y being as defined above and having the preferred meanings given above.

Especially important for A as a radical of a mono- or dis-azo dye in the dyes of formula (1) according to the invention are the dye radicals of formulae (8a), (8b), (8c), (8d), (8e), (8f), (8g) and (8h) indicated above, wherein (R₄)₀₋₃ and Z₁ are in each case as defined above and have the preferred meanings given above and R₄ in the dye radical of formula (8b) may in addition be C₁–C₄alkoxyanilino, and of the following formulae (19a), (19b), (19c), (19d), (19e), (19f), (19g), (19h), (19i), (19j), (19k), (19l), (19m), (19n), (19o), (19p), (19q), (19r) and (19s):

wherein (R₄)₀₋₃ denotes from 0 to 3 identical or different substituents from the group C₁–C₄alkyl, C₁–C₄alkoxy, halogen, carboxy and sulfo,

-   (R₅)₀₋₃ denotes from 0 to 3 identical or different substituents from     the group halogen, nitro, cyano, trifluoromethyl, sulfamoyl,     carbamoyl, C₁–C₄alkyl; C₁–C₄alkoxy unsubstituted or substituted by     hydroxy, sulfato or by C₁–C₄alkoxy; amino, C₂–C₄alkanoylamino,     ureido, hydroxy, carboxy, sulfomethyl, C₁–C₄alkylsulfonylamino and     sulfo, and -   Z₁ is a radical of formula (2a), (2c), (2d), (2e), (2f) or (2g),     preferably (2a), (2c), (2d) or (2e) and especially (2a), the     mentioned radicals having the definitions and preferred meanings     given above,

wherein R₆′ is sulfophenyl, C₂–C₄alkanoyl, benzoyl or a radical of formula (2b) or (2f) indicated above, wherein the radicals are as defined above and have the preferred meanings given above, preferably C₂–C₄alkanoyl or benzoyl,

wherein (R₇)₀₋₃ denotes from 0 to 3 identical or different substituents from the group C₁–C₄alkyl, C₁–C₄alkoxy, halogen, carboxy and sulfo,

wherein R₈ and R₁₀ are each independently of the other hydrogen, C₁–C₄alkyl or phenyl, and R₉ is hydrogen, cyano, carbamoyl or sulfomethyl,

wherein (R₄)₀₋₃ and Z₁ are in each case as defined above and have the preferred meanings given above,

wherein (R₄)₀₋₃ (R₅)₀₋₃ and (R₇)₀₋₃ are in each case as defined above and have the preferred meanings given above, (R₁₁)₀₋₃ and (R₁₂)₀₋₃ denote each independently of the other from 0 to 3 identical or different substituents from the group C₁–C₄alkyl, C₁–C₄alkoxy, halogen, carboxy and sulfo, and Z₁ is as defined above and has the preferred meanings given above.

The numbers on the naphthyl rings of the radicals of formulae (19a), (19b), (19c), (19f), (19g), (19h), (19l), (19m), (19n) and (19o) indicate the possible bonding positions.

(R₄)₀₋₃ in the disazoamino radicals of formulae (19q) and (19s) preferably denote from 1 to 3 sulfo groups.

Z₁ in the indicated dye radicals A is especially hydrogen.

Examples of suitable dye radicals A in the reactive dyes according to the invention are given in U.S. Pat. No. 5,484,899 (columns 13 to 40) and EP-A-0 623 655 (pages 11 to 27).

A is preferably the radical of a mono- or dis-azo dye.

In an especially preferred embodiment of the dyes according to the invention, A is a dye radical of formula (8a), (8b), (8c), (8d), (8e), (8f), (8g), (8h), (19d) or (19e), especially (8f) or (19d), wherein (R₄)₀₋₃, (R₅)₀₋₃ and Z₁ are in each case as defined above, and (R₄)₀₋₃ preferably denotes from 0 to 3 identical or different substituents from the group methyl, methoxy and sulfo, (R₅)₀₋₃ preferably denotes from 0 to 3 identical or different substituents from the group methyl, methoxy, β-hydroxyethoxy, β-sulfatoethoxy, sulfo, acetylamino and ureido, and Z₁ preferably may, if desired, be a fibre-reactive radical of formula (2a) wherein Y is vinyl or β-sulfatoethyl.

In a further especially preferred embodiment of the reactive dyes according to the invention, A is a dye radical of formula (19a), (19b), (19l) or (19n) indicated above wherein (R₄)₀₋₃, (R₅)₀₋₃ and Z₁ are in each case as defined above and have the preferred meanings given above.

A preferred embodiment of the present invention relates to reactive dyes of formula (1)

wherein

-   Q₁, Q₂, Q₃ and Q₄ are hydrogen, -   A is the radical of a monoazo or disazo chromophore, -   D is a radical of formula (9a), (9b), (9c), (9d) or (10a) indicated     above, especially (9a) or (9c)     wherein -   R′₅ is hydrogen, sulfo, or ethoxy unsubstituted or substituted in     the alkyl moiety by hydroxy or by sulfato, -   R′_(5a) is hydrogen, methyl, ethyl, methoxy, ethoxy, acetylamino,     propionylamino or ureido, -   (R₁₃)₀₋₂ denotes from 0 to 2 identical or different substituents     selected from the group halogen, C₁–C₄alkyl, C₁–C₄alkoxy and sulfo,     preferably methyl, methoxy and sulfo, and -   m is a number 2 or 3, preferably 2, -   Y₁ is a group —CH(Br)—CH₂—Br or —C(Br)═CH₂, -   Y is vinyl, β-chloroethyl or β-sulfatoethyl, preferably vinyl or     β-sulfatoethyl, and -   X is chlorine or fluorine, preferably chlorine.

The present invention relates also to a process for the preparation of the reactive dyes according to the invention, which comprises reacting with one another, in any order, approximately one molar equivalent of a compound of formula (20) A-NHQ₁  (20), approximately one molar equivalent of a compound of formula (21)

or suitable precursors of the compounds of formula (20) or (21), and approximately one molar equivalent of a halotriazine, preferably 2,4,6-trichloro- or 2,4,6-trifluoro-striazine, or, if using precursors of compounds of formula (20) or (21), converting the intermediates obtained into the desired dyes and, where appropriate, following on with a further transformation reaction, for example for transformation of a halogen atom on the triazine into any desired radical X; Q₁, Q₂, Q₃, Q₄, A, D and Y in each case being as defined above and having the preferred meanings given above.

The transformation, resulting from the use of precursors of compounds of formula (20) or (21), of intermediates into the end dyes consists especially of coupling reactions that result in azo dyes.

The halogen atom X on the triazine can be replaced by condensing the compound of formula (1) obtained wherein X is halogen, preferably fluorine or chlorine, with a compound X*—H wherein X* has the meanings given above for X except for halogen.

Such condensation reactions are known and described, for example, in EP-A-0 260 227 and U.S. Pat. No. 4,841,049.

The end product may optionally be subjected to a further transformation reaction. Such a transformation reaction is, for example, conversion of the radical Y having the meaning —CH₂CH₂-U, wherein U is as defined above, and a reactive group, present in D and capable of conversion into a vinyl group, into the vinyl form by treatment with dilute sodium hydroxide solution, e.g. conversion of the β-sulfatoethylsulfonyl or β-chloroethylsulfonyl group into the vinylsulfonyl radical. Such reactions are known per se.

Because the individual process steps mentioned above may be carried out in different orders as well as, where appropriate in some cases, simultaneously, different process variants are possible. The reaction is generally carried out in stepwise succession, the order of the simple reactions, known per se, between the individual reaction components being determined by the particular conditions.

A preferred variant of the preparation of the dyes according to the invention comprises reacting one molar equivalent of 2,4,6-trichloro- or 2,4,6-trifluoro-s-triazine first with one molar equivalent of a compound of formula (20) indicated above at approximately neutral pH and at low temperature, for example 0–5° C., and then with one molar equivalent of a compound of formula (22)

at a slightly acidic to neutral pH, for example pH 4.5–7.5, and at a temperature of, for example, 0–30° C., to form a compound of formula, (23)

and coupling the compound of formula (23) to one molar equivalent of a conventionally diazotised compound of formula (24) H₂N-D  (24) at a neutral to slightly acidic pH and at a temperature of, for example, 0–20° C., Q, Q₂, Q₃, Q₄, A, D and Y in each case being as defined above and having the preferred meanings given above and X being chlorine or fluorine.

The diazotisation of the amines of formula (24) is effected in customary manner, for example using a nitrite, e.g. an alkali metal nitrite, such as sodium nitrite, in a mineral acid medium, for example a hydrochloric-acid-containing medium, at temperatures of, for example, from −5 to 40° C., preferably from −5 to 10° C. and especially from 0 to 5° C.

The compounds of formulae (20), (22) and (24) are known or can be prepared in analogy to known compounds.

The compound of formula (22) is described, for example, in U.S. Pat. No. 4,897,469 and U.S. Pat. No. 5,424,405 and is prepared, for example, by first reacting the compound of formula(25)

which is known per se, with 2-mercaptoethanol, oxidising the resulting compound to form the sulfonyl compound of formula (26)

introducing a suitable leaving group U, for example —OSO₃H, and reducing the two nitro groups to form amino groups, resulting in the compound of formula(27)

and, if desired, introducing at both amino groups or at one of the amino groups, preferably the amino group in the 2-position, a group Q₂ Q₃ and/or Q₄, for example by means of alkylation with at least one of the compounds of formulae Q₂-X′, Q₃-X′and Q₄-X′, wherein X′ is halogen, for example chlorine, or by means of an addition reaction to an unsaturated precursor of the compound introducing the group Q₂ Q₃ and/or Q₄, for example acrylic acid, Q₂, Q₃ and Q₄ in each case being as defined above and having the preferred meanings given above. Such reactions are known and may be carried out, for example, in analogy to the procedure described in U.S. Pat. No. 6,222,067, by using the compound of formula (27) instead of the compound of formula (II) described in column 1 of U.S. Pat. No. 6,222,067, U being as defined above and having the preferred meaning given above, and proceeding as described in U.S. Pat. No. 6,222,067.

The reaction of the known compounds of formula (25) with 2-mercaptoethanol is carried out, for example, in a suitable solvent in the presence of potassium fluoride at elevated temperature, for example from 50 to 100° C. Suitable solvents therefor are, for example, water, lower alcohols, dioxane, toluene, xylenes, mono- or di-chlorobenzene, N,N-dimethylformamide and N-methylpyrrolidone.

The oxidation of the thioether compounds to form sulfones can be effected by various methods, for example using hydrogen peroxide with or without addition of suitable catalysts such as, for example, tungsten or vanadium compounds, or using peracetic acid, potassium permanganate or chromic acid, or using chlorine/hydrochloric acid each in an aqueous, aqueous-organic or organic medium.

The conversion of the hydroxyethylsulfonyl radical into a suitable reactive radical, for example into a sulfatoethylsulfonyl, thiosulfatoethylsulfonyl, phosphatoethylsulfonyl or vinylsulfonyl radical, is effected according to customary methods known per se.

The reduction of the nitro groups is likewise effected in a manner known per se, for example by catalytic hydrogenation using Pd/carbon in ethanol, ethyl acetate or tetrahydrofuran at from room temperature to about 40° C., or using Fe/hydrochloric acid or Fe/acetic acid in aqueous solution, resulting in the compound of formula (27).

The compound of formula (21) is obtained, for example, by coupling the compound of formula (22) to one molar equivalent of a conventionally diazotised compound of formula (24), at a neutral to slightly acidic pH and at a temperature of, for example, 0–20° C., Q₂, Q₃, Q₄, D and Y in each case being as defined above and having the preferred meanings given above.

The present invention accordingly relates to a reactive dye of formula

wherein

-   Q₂, Q₃, Q₄, D and Y in each case are as defined above and have the     preferred meanings given above.

The present invention relates also to a reactive dye of formula

which is obtained as indicated above, wherein

-   

Q₁, Q₂, Q₃, Q₄, A, X and Y in each case are as defined above and have the preferred meanings given above.

In a particular embodiment, A as a radical of a mono- or dis-azo dye in the dyes of formula (23) according to the invention is a radical of formula (19a), (19b), (19c), (19d), (19e), (19f), (19g), (19h), (19i), (19j), (19k), (19l), (19m), (19n), (19o), (19p), (19q), (19r) or (19s).

The reactive dyes according to the invention are present either in the form of their free acid or, preferably, in the form of their salts. Suitable salts are, for example, alkali metal, alkaline earth metal or ammonium salts or salts of an organic amine. Examples that may be mentioned are sodium, lithium, potassium or ammonium salts or a mono-, di- or tri-ethanolamine salt.

The reactive dyes according to the invention are suitable for dyeing and printing a wide variety of materials, especially hydroxyl-group-containing or nitrogen-containing fibre materials. Examples include paper, silk, leather, wool, polyamide fibres and polyurethanes, and especially all types of cellulosic fibre materials. Such fibre materials are, for example, natural cellulose fibres, such as cotton, linen and hemp, and cellulose and regenerated cellulose. The dyes according to the invention are also suitable for dyeing or printing hydroxyl-group-containing fibres present in blend fabrics, for example blends of cotton and polyester fibres or polyamide fibres.

The present invention accordingly relates also to the use of reactive dyes according to the invention in the dyeing or printing of hydroxyl-group-containing or nitrogen-containing, especially cotton-containing, fibre materials.

The reactive dyes according to the invention can be applied to the fibre material and fixed to the fibre in a variety of ways, especially in the form of aqueous dye solutions or dye print pastes. They are suitable both for the exhaust process and for dyeing in accordance with the pad-dyeing process; they can be used at low dyeing temperatures and require only short steaming times in the pad-steam process. The degrees of fixing are high and unfixed dye can be washed off readily, the difference between the degree of exhaustand the degree of fixing being remarkably small, that is to say the soaping loss is very small. The reactive dyes according to the invention are also suitable for printing, especially on cotton, and also for printing nitrogen-containing fibres, for example wool or silk or blend fabrics that contain wool.

The dyeings and prints produced using the reactive dyes according to the invention have a high tinctorial strength and a high fibre-dye binding stability in both the acidic and the alkaline range, and also good fastness to light and very good wet-fastness properties, such as fastness to washing, to water, to seawater, to cross-dyeing and to perspiration. The dyeings obtained exhibit fibre levelness and surface levelness.

The following Examples serve to illustrate the invention. Unless otherwise indicated, the temperatures are given in degrees Celsius, parts are parts by weight and percentages relate to percent by weight. Parts by weight relate to parts by volume in a ratio of kilograms to liters.

EXAMPLE 1

-   a) 217 parts of potassium fluoride are introduced into a solution of     500 parts of 2,4dinitro-1-chlorobenzene in 590 parts of     N,N-dimethylformamide (DMF) and the reaction mixture is stirred for     5 hours at room temperature. 350 parts of 2-mercaptoethanol are then     added dropwise, whereupon the internal temperature rises to from 60     to 65° C., and stirring is then carried out for about 15 hours at     that temperature. Then, any starting materials still present are     made to react by adding 34 parts of potassium carbonate. Finally,     the mixture is left to cool to room temperature, salts are filtered     off and the filtrate is concentrated. The oily crude product is     discharged onto water, whereupon a yellow crystalline precipitate     separates out. After filtering off under suction, washing and     drying, 2-[2,4-dinitrophenylsulfanyl]ethanol is obtained in an     almost quantitative yield and high purity. -   b) A suspension of 220 parts of Oxone® in 150 parts of water is     introduced into a solution of 140 parts of     2-[2,4-dinitrophenylsulfanyl]ethanol in 1100 parts of methanol and     the reaction mixture is refluxed for about 1 hour, with stirring.     There are then added 3.5 parts of ammonium heptamolybdate dissolved     in a small amount of water, and also 30 parts of 30% hydrogen     peroxide, and stirring is carried out, under reflux, until the     reaction has ceased. After the reaction is complete, saturated     sodium disulfite solution is added until peroxide is no longer     detectable; the mixture is cooled to from 0 to 5° C., salts are     filtered off and the filtrate is concentrated. The product that     crystallises out is filtered off under suction, washed and dried.     2-[2,4-Dinitrophenylsulfonyl]ethanol is obtained in a good yield. -   c) 105 parts of 2-[2,4-dinitrophenylsulfonyl]ethanol are slowly     introduced, at from 0 to 5° C., into 380 parts of sulfuric acid     monohydrate and stirring is carried out for 14 hours at that     temperature. The brown solution obtained is then slowly discharged     onto a mixture of ice and 20% sodium chloride solution, whereupon a     yellowish suspension is formed. The precipitate is filtered off and     washed first with 1000 parts of cold 20% sodium chloride solution     and then with 200 parts of ice-water. After drying,     2-[2,4-dinitrophenylsulfonyl]ethyl hydrogen sulfate is obtained in a     very good yield and very good purity. -   d) 19 parts of acetic acid are added, at 80° C., to a suspension of     180 parts of iron in 500 parts of water and stirred for 5 minutes.     The mixture is then cooled to 60° C. and 150 parts of     2-[2,4-dinitrophenylsulfonyl]ethyl hydrogen sulfate are slowly     introduced. After 30 minutes, the reaction mixture is cooled to from     0 to 5° C., and the insoluble constituents are filtered off. The     filtrate is concentrated. After drying, the compound of     formula (101) is obtained

EXAMPLE 2

17.3 Parts of an Amine of Formula D₁₀-NH₂ Wherein D₁₀ is a Radical of Formula

are introduced into 215 parts of water and stirred well. At 0° C., 25 parts of 4N sodium nitrite solution are added to the solution obtained, and then 20 parts of concentrated hydrochloric acid are slowly added dropwise at from 0 to 5° C. Stirring is carried out for 1 hour at that temperature.

EXAMPLE 3

14.5 Parts of an Amine of Formula D₁₁-NH₂ Wherein D₁₁ is a Radical of Formula

are introduced into 60 parts of water and stirred well. At 10° C., first 13 parts of 4N sodium nitrite solution and then 23.4 parts of 31% naphthalenesulfonic acid solution are added to the suspension obtained. Stirring is then carried out for 3 hours at from 15 to 20° C.

EXAMPLES 4 to 32

The diazo compounds of the amines indicated in Table 1 can be prepared analogously to the procedure described in Example 2 or 3 by using, instead of the amine of formula D₁₀-NH₂ or D₁₁-NH₂ indicated in Example 2 or 3, an equimolar amount of an amine of formula D_(xy)-NH₂ indicated in Table 1.

TABLE 1 Amine Ex. D_(xy)—NH₂ D_(xy) 4 D₁₂—NH₂ D₁₂ =

5 D₁₃—NH₂ D₁₃ =

6 D₁₄—NH₂ D₁₄ =

7 D₁₅—NH₂ D₁₅ =

8 D₁₆—NH₂ D₁₆ =

9 D₁₇—NH₂ D₁₇ =

10 D₁₈—NH₂ D₁₈ =

11 D₁₉—NH₂ D₁₉ =

12 D₂₀—NH₂ D₂₀ =

13 D₂₁—NH₂ D₂₁ =

14 D₂₂—NH₂ D₂₂ =

15 D₂₃—NH₂ D₂₃ =

16 D₂₄—NH₂ D₂₄ =

17 D₂₅—NH₂ D₂₅ =

18 D₂₆—NH₂ D₂₆ =

19 D₂₇—NH₂ D₂₇ =

20 D₂₈—NH₂ D₂₈ =

21 D₂₉—NH₂ D₂₉ =

22 D₃₀—NH₂ D₃₀ =

23 D₃₁—NH₂ D₃₁ =

24 D₃₂—NH₂ D₃₂ =

25 D₃₃—NH₂ D₃₃ =

26 D_(34a)—NH₂—D_(34r)—NH₂ D_(34a)—D_(34r) =

T₁: 26a D_(34a)—NH₂ D_(34a)

26b D_(34b)—NH₂ D_(34b)

26c D_(34c)—NH₂ D_(34c)

26d D_(34d)—NH₂ D_(34d)

26e D_(34e)—NH₂ D_(34e)—NHCH₂CH₂OH 26f D_(34f)—NH₂ D_(34f)—N(CH₂CH₂OH)₂ 26g D_(34g)—NH₂ D_(34g)

26h D_(34h)—NH₂ D_(34h)

26i D_(34i)—NH₂ D_(34i)—NH—(CH₂)₂—O—(CH₂)₂—OH 26j D_(34j)—NH₂ D_(34j)—NHCH₂CH₂SO₃H 26k D_(34k)—NH₂ D_(34k)

26l D_(34l)—NH₂ D_(34l)

26m D_(34m)—NH₂ D_(34m)—NH—(CH₂)₂—SO₂—(CH₂)₂—Cl 26n D_(34n)—NH₂ D_(34n)—NH—(CH₂)₂—O—(CH₂)₂—SO₂—(CH₂)₂—Cl 26o D_(34o)—NH₂ D_(34o)

26p D_(34p)—NH₂ D_(34p)

26q D_(34q)—NH₂ D_(34q)

26r D_(34r)—NH₂ D_(34r)

27 D₃₅—NH₂ D₃₅ =

28 D₃₆—NH₂ D₃₆ =

29 D₃₇—NH₂ D₃₇ =

30 D₃₈—NH₂ D₃₈ =

31 D₃₉—NH₂ D₃₉ =

32 D₄₀—NH₂ D₄₀ =

EXAMPLE 33

9.3 parts of cyanuric chloride are suspended in 100 parts of ice/water mixture and stirred. A solution of 27 parts of 7-(4-amino-2-ureido-phenylazo)-naphthalene-1,3,6-trisulfonic acid in 200 parts of water is added dropwise at from 0 to 5° C. and at a pH of about 7 to the resulting suspension and the hydrochloric acid that forms is neutralised by adding 2N sodium hydroxide solution. A solution of 15.0 parts of the compound of formula (101) according to Example 1 in 120 parts of water is then added dropwise at from 3 to 5° C. and at a pH of from 5 to 5.5 to the reaction solution and the latter is then stirred for a further 2 to 3 hours at from 5 to 30° C. and at a pH of from 5 to 7.5. The pH is then adjusted to 4.5. The solution comprises the reactive dye of formula (102)

which serves as the coupling component in the following reaction step.

The diazonium salt solution according to Example 3 is added dropwise over the course of about 1 hour to the solution of the coupling component. After about 2 hours at from 2 to 14° C. and at a pH of from 4.5 to 5.5, the reaction is complete. The dye solution obtained is desalted and freeze-dried; there is obtained the dye of formula

which dyes cellulose fibres golden-yellow shades having good all-round fastness properties.

EXAMPLE 34

27 parts of 7-(4-amino-2-ureido-phenylazo)-naphthalene-1,3,6-trisulfonic acid are dissolved in 400 parts of water at neutral pH and, over the course of about 30 minutes, 8.5 parts of cyanuric fluoride are added dropwise at from 0 to 2° C. 15.8 parts of the compound of formula (101) according to Example 1 in 120 parts of water are added dropwise to the reaction solution at from 2 to 20° C. and at a pH of from 5.5 to 6 and the resulting solution is then cooled to from 0 to 5° C. The solution comprises the reactive dye of formula (104)

which serves as the coupling component in the following reaction step.

The diazonium salt solution according to Example 3 is added dropwise to the solution of the coupling component. Coupling is carried out at from 2 to 15° C. and at a pH of from 5 to 7. After the reaction is complete, the pH is increased to 10, and the reaction solution is stirred for about 20 minutes at room temperature and neutralised. The resulting dye solution is desalted and freeze-dried; there is obtained the dye of formula (105)

which dyes cellulose fibres strong yellow shades having good all-round fastness properties.

EXAMPLE 35

14.8 parts of cyanuric chloride are suspended in 150 parts of ice/water mixture and stirred. A solution of 42.2 parts of 8-amino-1-hydroxy-2-(1-sulfonaphth-2-yl-azo)-naphthalene-3,6-disulfonic acid in 600 parts of water is added dropwise at from 0 to 5° C. and at a pH of about 7 to the resulting suspension and the hydrochloric acid that forms is neutralised by adding 2N sodium hydroxide solution. A solution of 25.0 parts of the compound of formula (101) according to Example 1 in 180 parts of water is then added dropwise to the reaction solution, whereupon the pH falls to about 3.5. The reaction solution, which comprises the reactive dye of formula (106)

is then stirred for about from 2 to 3 hours at from 5 to 30° C. and at a pH of from 3.5 to 5 and is subsequently cooled to from 0 to 5° C.

A diazonium salt solution prepared according to Example 3 comprising 22.5 parts of an amine D₁₁-NH₂ wherein D₁₁ corresponds to a radical of the formula indicated in Example 3 is added dropwise to the solution of the coupling component and is coupled at from 0 to 25° C. and at a pH of from 4 to 6. The resulting dye solution is desalted and freeze-dried. There is obtained the dye of formula (107)

which dyes cellulose fibres in yellow-tinged red shades having good all-round fastness properties.

Examples 36 to 82: Analogously to the procedure described in Example 33, there can be prepared further reactive dyes of the general formula

wherein the variable D_(xy) is in each case the radical indicated in Table 2 and those radicals have the meanings indicated in each case in Example 2 and Table 1. The reactive dyes dye cellulose fibres in yellow shades having good all-round fastness properties.

TABLE 2 Ex. D_(xy) 36 D₁₀ 37 D₁₂ 38 D₁₃ 39 D₁₄ 40 D₁₅ 41 D₁₆ 42 D₁₇ 43 D₁₈ 44 D₁₉ 45 D₂₀ 46 D₂₁ 47 D₂₂ 48 D₂₃ 49 D₂₄ 50 D₂₅ 51 D₂₆ 52 D₂₇ 53 D₂₈ 54 D₂₉ 55 D₃₀ 56 D₃₁ 57 D₃₂ 58 D₃₃ 59 D_(34a) 60 D_(34b) 61 D_(34c) 62 D_(34d) 63 D_(34e) 64 D_(34f) 65 D_(34g) 66 D_(34h) 67 D_(34i) 68 D_(34j) 69 D_(34k) 70 D_(34l) 71 D_(34m) 72 D_(34n) 73 D_(34o) 74 D_(34p) 75 D_(34q) 76 D_(34r) 77 D₃₅ 78 D₃₆ 79 D₃₇ 80 D₃₈ 81 D₃₉ 82 D₄₀

EXAMPLES 83 to 129

Analogously to Examples 33 to 35, there can be prepared further reactive dyes of the general formula

from the dyes A-NHQ₁, the diazo components D_(xy)-NH₂ (where n=1) and, where appropriate, the compounds X*—H, the variables A, Q₁, D_(xy) and X in each case being the radicals indicated in Table 3 and n being a number 0 or 1; the variables D_(xy) are as defined above in Table 1 and Examples 2 and 3.

TABLE 3 Dye Diazo component Ex. A—NHQ₁ D_(xy)—NH₂ X bzw. X* 83

D₁₁—NH₂ Cl 84

D₁₁—NH₂ Cl 85

D₁₁—NH₂

86

D₁₀—NH₂ Cl 87

D₁₉—NH₂ F 88

D₁₂—NH₂ Cl 89

D₁₇—NH₂ Cl 90

D₁₂—NH₂ Cl 91

D₁₁—NH₂ F 92

D₁₁—NH₂ Cl 93

D₁₉—NH₂ Cl 94

D₁₁—NH₂ Cl 95

D₁₁—NH₂ Cl 96

D₁₁—NH₂ Cl 97

D₁₂—NH₂

98

D₁₉—NH₂ Cl 99

D₁₁—NH₂ F 100

D₁₂—NH₂ Cl 101

D₁₂—NH₂ Cl 102

D₁₁—NH₂ Cl 103

D₁₈—NH₂ Cl 104

D₁₂—NH₂ Cl 105

D₁₁—NH₂ F 106

D₁₆—NH₂ Cl 107

D₁₁—NH₂ F 108

D₁₁—NH₂ Cl 109

D₁₁—NH₂ HN(CH₂CH₂OH)₂ 110

D₁₁—NH₂ F 111

D₁₁—NH₂ Cl 112

D₁₈—NH₂ F 113

D₁₁—NH₂ Cl 1:2 Cr-Komplex 114

D₁₁—NH₂ Cl 115

D₁₁—NH₂ F 116

D₁₁—NH₂ Cl 117

D₁₀—NH₂ Cl 118

D₁₈—NH₂ Cl 119

D₁₁—NH₂ Cl 120

D₁₁—NH₂ Cl 121

D₁₁—NH₂ Cl 122

D₁₁—NH₂ Cl 123

D₁₁—NH₂ Cl 124

D₁₁—NH₂ Cl 125

D₁₁—NH₂ Cl 126

D₁₁—NH₂ Cl 127

D₁₉—NH₂ F 128

D₁₂—NH₂ F 129

D₁₂—NH₂ Cl Dyeing Procedure I

100 parts of cotton fabric are placed at 60° C. in 1500 parts of a dyebath containing 45 g/l of sodium chloride and 2 parts of the reactive dye obtained according to Example 33. After 45 minutes at 60° C., 20 g/l of calcined soda are added. Dyeing is continued at that temperature for a further 45 minutes. The dyed goods are then rinsed, soaped at the boil for a quarter of an hour with a non-ionic detergent, rinsed again and dried.

As an alternative to that procedure, dyeing can be carried out at 80° C. instead of at 60° C.

Dyeing Procedure II

0.1 part of the dye according to Example 33 is dissolved in 200 parts of water, and 0.5 part of sodium sulfate, 0.1 part of a levelling agent (based on the condensation product of a higher aliphatic amine and ethylene oxide) and 0.5 part of sodium acetate are added. The pH is then adjusted to a value of 5.5 with acetic acid (80%). The dyebath is heated at 50° C. for 10 minutes and then 10 parts of a woollen fabric are added. The dyebath is heated to a temperature of 100° C. in the course of about 50 minutes and dyeing is carried out at that temperature for 60 minutes. The dyebath is then cooled to 90° C. and the dyed goods are removed. The woollen fabric is washed with hot and cold water, then spun and dried.

Printing Procedure

While stirring rapidly, 3 parts of the dye obtained according to Example 33 are sprinkled into 100 parts of a stock thickener containing 50 parts of 5% sodium alginate thickener, 27.8 parts of water, 20 parts of urea, 1 part of sodium m-nitrobenzenesulfonate and 1.2 parts of sodium hydrogen carbonate. The print paste so obtained is used to print a cotton fabric; drying is carried out and the resulting printed fabric is steamed in saturated steam at 102° C. for 2 minutes. The printed fabric is then rinsed, if desired soaped at the boil and again rinsed, and then dried. 

1. A reactive dye of formula (1)

wherein Q₁, Q₂, Q₃ and Q₄ are each independently of the others hydrogen or unsubstituted or substituted C₁–C₄alkyl, A is the radical of a monoazo, polyazo, metal complex azo, anthraquinone, phthalocyanine, formazan or dioxazine chromophore, D is the radical of a diazo component, of the benzene or naphthalene series, X is halogen, 3-carboxypyridin-1-yl, 3-Carbamoylpyridin-1-yl, hydroxy, C₁–C₄alkoxy unsubstituted or substituted in the alkyl moiety, phenoxy unsubstituted or substituted in the phenyl moiety, C₁–C₄alkylthio unsubstituted or substituted in the alkyl moiety, unsubstituted or substituted amino, or an N-heterocycle which may or may not contain further hetero atoms, and Y is vinyl or a radical —CH₂—CH₂—U and U is a group removable under alkaline conditions selected from the group consisting of —Cl, —Br, —F, —OSO₃H, —SSO₃H, —OCO—CH₃, —OPO₃H₂, —OCO—C₆H₅, —OSO₂—C₁–C₄alkyl or —OSO₂—N(C₁–C₄alkyl)₂.
 2. A reactive dye according to claim 1, wherein Q₁, Q₂, Q₃ and Q₄ are hydrogen.
 3. A reactive dye according to claim 1, wherein X is fluorine or chlorine.
 4. A reactive dye according to claim 1, wherein D corresponds to a radical of formula (9) or (10)

wherein (R₄)₀₋₃ and (R₁₃)₀₋₃ each independently of the other denote from 0 to 3 identical or different substituents selected from the group halogen, C₁–C₄alkyl, C₁–C₄alkoxy, carboxy and sulfo, K₃ is the radical of a coupling component of formula (11a) or (11b)

and Z and Z₁ are each independently of the other a radical of formula (2a), (2c), (2d), (2e) or (2f) —SO₂—Y  (2a), —CONR₂—(CH₂)_(m)—SO₂—Y  (2c), —NH—CO—CH(Hal)—CH₂—Hal  (2d), —NH—CO—C(Hal)═CH₂  (2e) or

wherein R_(1a) and R₂ are hydrogen, Hal is bromine, Y is vinyl, β-chloroethyl or β-sulfatoethyl, T₁ is C₁–C₄alkoxy, C₁–C₄alkylthio, hydroxy, amino; N-mono- or N,N-di-C₁–C₄alkylamino unsubstituted or substituted in the alkyl moiety by hydroxy, sulfato or by sulfo; morpholino; or phenylamino or N—C₁–C₄alkyl-N-phenylamino, wherein the alkyl is unsubstituted or substituted by hydroxy, sulfo or by sulfato, each unsubstituted or substituted in the phenyl ring by sulfo, carboxy, acetylamino, chlorine, methyl or by methoxy; or naphthylamino unsubstituted or substituted by from 1 to 3 sulfo groups, or is a fibre-reactive radical of formula (3c′) or (3d′)

and Y is as defined above, X₁ is chlorine or fluorine, m is a number 2 or 3, R′₅ is hydrogen, sulfo, or C₁–C₄alkoxy unsubstituted or substituted in the alkyl moiety by hydroxy or by sulfato, R′_(5a) is hydrogen, C₁–C₄alkyl, C₁–C₄alkoxy, C₂–C₄alkanoylamino, ureido or a radical of formula (2f) wherein the radicals R_(1a), T₁ and X₁ are as defined above.
 5. A reactive dye according to claim 4, wherein the radical D corresponds to a radical of formula (9a), (9b), (9c), (9d) or (10a)

wherein R′₅ is hydrogen, sulfo, or ethoxy unsubstituted or substituted in the alkyl moiety by hydroxy or by sulfato, R′_(5a) is hydrogen, methyl, ethyl, methoxy, ethoxy, acetylamino, propionylamino or ureido, (R₁₃)₀₋₂ denotes from 0 to 2 identical or different substituents selected from the group consisting of halogen, C₁–C₄alkyl, C₁–C₄alkoxy and sulfo, Y₁ is a group —CH(Br)—CH₂—Br or —C(Br)═CH₂, Y is vinyl, β-chloroethyl or β-sulfatoethyl, and m is a number 2 or
 3. 6. A reactive dye according to claim 1, wherein A is the radical of a mono- or dis-azo dye.
 7. A reactive dye according to claim 1, wherein A is a dye radical of formula (8a), (8b), (8c), (8d), (8e), (8f), (8g), (8h), (19d) or (19e),

wherein (R₄)₀₋₃ denotes from 0 to 3 identical or different substituents selected from the group consisting of methyl, methoxy and sulfo, (R₅)₀₋₃ denotes from 0 to 3 identical or different substituents selected from the group consisting of methyl, methoxy, β-hydroxyethoxy, β-sulfatoethoxy, sulfo, acetylamino and ureido, and Z₁ may optionally, be a fibre-reactive radical of formula (2a) —SO₂—Y  (2a) wherein Y is vinyl or β-sulfatoethyl.
 8. A reactive dye according to claim 1, wherein A is a dye radical of formula (19a), (19b), (19l) or (19n)

wherein (R₄)₀₋₃ denotes from 0 to 3 identical or different substituents selected from the group consisting of methyl, methoxy and sulfo, (R₅)₀₋₃ denotes from 0 to 3 identical or different substituents selected from the group consisting of methyl, methoxy, β-hydroxyethoxy, β-sulfatoethoxy, sulfo, acetylamino and ureido, and Z₁ may, optionally, be a fibre-reactive radical of formula (2a) —SO₂—Y  (2a) wherein Y is vinyl or β-sulfatoethyl.
 9. A method of dyeing or printing hydroxyl-group-containing or nitrogen-containing fibre materials, which comprises contacting said materials with a tinctorially effective amount of a reactive dye according to claim
 1. 10. A method according to claim 9, wherein cellulosic fibre materials, are dyed or printed.
 11. A reactive dye of formula (21)

wherein Q₂, Q₃ and Q₄ are each independently of the others hydrogen or unsubstituted or substituted C₁–C₄alkyl, D is the radical of a diazo component, of the benzene or naphthalene series, and Y is vinyl or a radical —CH₂—CH₂—U and U is a group removable under alkaline conditions selected from the group consisting of —Cl, —Br, —F, —OSO₃H, —SSO₃H, —OCO—CH₃, —OPO₃H₂, —OCO—C₆H₅, —OSO₂—C₁–C₄alkyl or —OSO₂—N(C₁–C₄alkyl)₂.
 12. A reactive dye of formula (23)

wherein Q₁, Q₂, Q₃ and Q₄ are each independently of the others hydrogen or unsubstituted or substituted C₁–C₄alkyl, A is the radical of a monoazo, polyazo, metal complex azo, anthraquinone, phthalocyanine, formazan or dioxazine chromophore, X is halogen, 3-carboxypyridin-1-yl, 3-carbamoylpyridin-1-yl, hydroxy, C₁–C₄alkoxy unsubstituted or substituted in the alkyl moiety, phenoxy unsubstituted or substituted in the phenyl moiety, C₁–C₄alkylthio unsubstituted or substituted in the alkyl moiety, unsubstituted or substituted amino, or an N-heterocycle which may or may not contain further hetero atoms, and Y is vinyl or a radical —CH₂—CH₂—U and U is a group removable under alkaline conditions selected from the group consisting of —Cl, —Br, —F, —OSO₃H, —SSO₃H, —OCO—CH₃, —OPO₃H₂, —OCO—C₆H₅, —OSO₂—C₁–C₄alkyl or —OSO₂—N(C₁–C₄alkyl)₂.
 13. A process for the preparation of a reactive dye according to claim 1, which comprises reacting one molar equivalent of 2,4,6-trichloro- or 2,4,6-trifluoro-s-triazine first with one molar equivalent of a compound of formula (20) A-NHQ₁  (20), and then with one molar equivalent of a compound of formula (22)

 to form a compound of formula (23)

and coupling the compound of formula (23) to one molar equivalent of a conventionally diazotised compound of formula (24) H₂N-D  (24) C, Q₁, Q₂, Q₃, Q₄, A, D and Y in each case being as defined in claim 1 and X being chlorine or fluorine. 